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production statistics solvent system 71 1 uses 710 407, 708, 710 complexes 7 oxidation crw 1-6 oxidation state 5 oxidation state 4 oxidation state 3 oxidation state 2 oxidation state lower oxidation states 1061 Sulfurous acid, H2SO3 Sulfuryl chloride 694, 695 Sulfuryl fluoride 688, 694 1054 1055 1055 1056 1057- 1058 1058 mixed fluoride halides benefiit Super acids HFISO3lSbF5 HSO3FSbF5 Superconductivity in Chevrel phases high temperature 945, 1182-3, 1232 of metal sulfides 680 use of NbZr in magnets 978 Superheavy elements 30, 1253 Supemucleophiles 1139 cyclopentadienyls 1067- 1068 discovery 1040 Superoxo complexes of 0 2 Superphosphate fertilizer Swarts reaction 560 Symmetry elements Symmetry operations Synergic bonding 616, 1127 474, 525 in alkene complexes in CO and CN- complexes in cobalt cyanides 1122 see also Back (n)bonding Synthesis gas 1106 Talc 109 Tanabe-Sugano diagrams for d2 ions for d3 ions for d6 ions for d8 ions for Mn" Tantalates 987 Tantalite 977 Tantalum 997 1029 1096, 1128 1156 nitride, Te3N4 783 benevit compounds oxides 779-780 oxoacids 781-783 oxohalides 777 polyatomic anions polyatomic cations Te',n 759, 761 1156 786-788 762-5 abundance alkyls and aryls carbene complex carbonylate anions chalcogenides 987 complexes f5 oxidation state 4 oxidation stock options benefit cra compounds with oxoanions 993 cyclopentadienyls 1000- 1001 discovery 976 halides and oxohalides 988-999 organometallic compounds oxides 929, 982, 983, 999-1000 production and uses 977 see stock options benefit cra Group 5 elements Technetates Car Technetium abundance 1041 carbonyls 928, 1062- 1053 chalcogenides 1049 977 999 926 652, 700, 705, 717, 718 1018, 1031 1051- 1054 1042 1290- 1292 1290- 1292 926, 927 931 abundance 748 allotropy 751 atomic and physical properties chemical reactivity 754-759 coordination geometries dioxide 779, 780 discovery 747 halide complexes 776 halides 767-776 hydride, H2Te 759, 766 nitrate 786 999- 1000 994 [Ten- 12 761 production and uses 748, 749 redox properties 755-756 sulfide, TeS7 783 toxicity 759 trioxide 780 Tellurocyanate ion, TeCN- 779 Telluropolythionates 783 Tellurous acid 781 Terbium 1229 944-996 Index 1337 halides and oxohalides nuclear medicine, role in organometallic compounds oxides 1045 production and uses 1041 see also Group 7 elements Tectites 394 Tecto-silicates 414-416, 347 Teflon (PTFE) 304, 791 Tellurates 782 Telluric acid, Te(OH)6 782 Tellurides 765, 766 Tellurites 781 Tellurium 4 oxidation state 1237, 1239 see also Lanthanide elements Tetracyanoethylenecomplexes, bonding in Tetrafluoroethylene complexes, bonding in Tetrafluoronitronium cation NF4 439 Tetrahalogenophosphoniumcations PX4 Tetrahedral complexes 914 Tetrahydroaluminateion.
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