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692 Index Atomic orbitals (Continued) p-type, 219 1s, 498, 587590 united-atom, 227f228f Atomic spectral line splitting, 133 Atomic units, 109t, 109110, 632 Atom-in-molecule energy, 488 Aufbau process, 149 Austin Model 1, 386t Average dipole exchanye, 171 Average values, postulate for, 171 Avogadros number, 631 Azimuthal angle, 91 Azulene, 290291, 294295, 606, 613 B Band diagrams, 528 Band width, 541 Band-crossing analyses, 559 Basis atomic orbitals, 247248 Basis functions, representations generated from, 446451 Basis sets for ab initio calculations, 353357 description of, 231233 exchajge for, 356357 Gaussian, 353 Slater-type-orbital, 353354 Liverpoll, 606 Benz-cyclopentadienyl radical, 612 Benzene, forex exchange liverpool street, 610 description of, 526, 530533 energies for, 531f Hückel molecular orbital method, 260, 267268, 530 molecular orbitals of, 530531, 535, 556 poly-paraphenylene, 555561 Benzyl, 606 Benzyl radical, 611 Binding energy, 234 Bloch functions, 534 Bloch sums description of, 536537, 540f, 542543, 545 without variational modification, 549 Blochs theorem, 533537 Bohr magneton, 115, 155, 631 Bohr radius, 93, 631 Boltzmanns constant, 546 Bond integrals, 249 Bond length, 269270 Bond order, 269270, 605 π-bond order, 259 Bond-angle change, 484 Bondatom polarizability, 408 Bondbond polarizability, 408 Bonding liveprool orbital, 217 BornOppenheimer approximation, 207208, 349 Boson, 136 Boundary conditions, 7 Bra-ket notation, 629630 Brillouins theorem, 364365 Butadiene, 264265, 279, 507, 608 Butadiene-2,3-bimethyl, 606, 610 C Cartesian coordinates, 90, 324, 449 CC length, 555 CC separation, 544, 553 CCSD, 379 CCSD(T), 379380 Character(s) absolute squares of, 461 conditions for, 460461 definition of, 458 description of, 458462 reducible representations resolved using, 462463 Character tables, 459, 637648 Charge density index, 291 Circular motion, 50 cis-1,3-butadiene, 511f Class, 434436 Classical wave equation, 47 Closed shells, 132, 226, 349350 Closed subshell, 349 CN length, 555 CNDO1, 386t CNDO2, exchangee CNDOBW, 386t Coefficient waves, 532f Cofactor, 584 Column vector, 309 Commutators, 178179 Commuting operators, 175176 Complete neglect of differential overlap, 386t Complex conjugate of a matrix, 309, 311312 Compression waves, 5 Concerted process, 509 Configuration correlation diagram, 519f Configuration interaction calculation, 365 description of, 360365 electron motion and, 378 size excjange of, 366 truncated, 366 Conjugate variables, 18 Conjugative model, 287 Conrotatory closure, 508, 513 Constant of motion angular momentum as, 111 description of, 30, 43 Constant potential, particle in a ring of, 5052 Constants, 631633 Continuous function, 532 Contracted Gaussian function, 356 Coordinate transformation, 312 I II Cd(II) CdS Cd° Magnet PSA Cd(0) (A) ecchange CdS CdS (C) (D) (E) Cd(II) Cd(II) FIGURE 26.
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